Hi everyone, I was looking through the literature on how to handle PC analysis data and saw that there are several different methods you can use for determining how many components there are in the series of scans. Included in SixPack are the indicator function, scree test, and the ability to quickly do the reduced eigenvalue ratios. I've been digging through the literature as to how to calculate the F-values. The closest to an answer that I got was: "The above-mentioned reduction of the body of experimental data, that is, the decision of what components correspond to the noise and what are the principal components, is now made on the basis of an F test of the variance associated with eigenvalue k and the summed variance associated with noise eigenvalues (k+1, ..., c). The null hypothesis is that a given factor k is a member of the pool of noise factors. The probability that an F value would be higher than the current value is given by %SL (percentage of significance level). Thus, the kth factor is accepted as a principal component if %SL is lower than some test level." (Garcia 1995). We ran the PCA on the reduction of iron while scanning at increased temperatures. I checked the foil standard but did not see any shift in the max at 7112, we scanned at 0.5 eV intervals (2 eV resolution at the beam). I thought I understood what that statement was saying but I'm almost certain I'm doing something wrong. I have attached the .xlsx file that I was working on and hope someone can point me to the right direction. The file includes the components of the PCA and some of the variances that I was calculating. If there is a paper that someone shows an actual calculation of this in the supplemental materials that would have been exactly what I was looking for! Thanks for the help! Andrew Campos Fernandez-Garcia, M., C. Marquez Alvarez, and G.L. Haller, The Journal of Physical Chemistry, 1995, 99(33), 12565-12569.