Dear Dr. English,
unfortunately, I am not a metals and intermetallics expert. I mostly
work on oxides and related phases.
Nevertheless, I've now ordered your original TMS paper from our library.
As soon as I've found the time to read your analysis, I'll get in touch
with you.
There might be a good chance that EXAFS could give additional insight
into these fine domain structures, since - as you wrote - many atoms
will have a large number of wrong next neighbors. Maybe, there are also
some intermetallics experts on this list, who could comment on this more
knowledgeably.
Best regards,
Dominik Samuelis
Dear Sir: I just ran across your exchange of ideas on FeCo order etc.
about this time last year. I did some experiments in the mid 60s
(Trans. Met. Soc AIME 236 (1966) 14ff.) on FeCo2V and showed that the
superlattice xray line [100} can be seen in brine-quenched thin strips
if the XRD is done with CoKa radiation. The lines are very broad in
as-quenched state and the peak narrows gradually with time of
reheating to a few hundred degrees C.
The interpretation was that we were seeing APB domains which were
unexpected but seemed obvious in hindsight--two interpenetrating,
multiply-connected domains sort of like "swiss cheese" (J. W. Cahn
called it "sponge" at the time--he wrote an elegant mathematical
analysis that appeared in Acta Met.). The "scale" of interconnection
changes with time at temperature as the structure coarsens to reduce
the energy associated with APB. I thought the picture was confusing
since "perfect order with very fine domain size" could as well be
descri bed as partial, or incomplete order due to large number of
wrong near neighbors. I don't know if there are other alloys or
chemical combinations in which B2 order is present with very fine
domain structure such as I described. I am not aware of any other work
that confirmed or reinterpreted my results. Any comments?
--
Dr. Dominik Samuelis
d.samuelis@fkf.mpg.de
Max-Planck-Institut für Festkörperforschung
Heisenbergstr. 1
70569 Stuttgart
Germany
Phone +49-711-689-1769
Fax +49-711-689-1722
Web http://www.fkf.mpg.de/maier/