Cu K edge XANES stds
Hi mailing list, I am hoping someone is willing to share their Cu K-edge XANES spectra from biological Cu thiol complexes. I’m particularly interested in Cu(I/II)-GSH, Cu(I/II)-Cys or similar. I need a sanity check on some fluorescence data I am wrangling. Can anyone help? Best regards, Simon This mail was composed on the move via my phone. Apologies for any typos. Florey Institute of Neuroscience and a Mental Health Melbourne Brain Centre 30 Royal Pde Parkville, 3052 VIC
Hi Simon, Since you are just looking for a sanity check (on what??) here are some Cu-S standards for you. They were published in DOI: 10.1021/es304736y. The Cu-cys sample is not a pure phase, but probably a mixture of cysteine/cystine. But it is likely mostly Cu(I). Further discussion is available in the SI of the paper above. The file is from an old, old version of Athena (0.8x)... hopefully it works for you. Best, Drew Latta ====================================== Drew E. Latta, Ph.D. Asst. Research Scientist The University of Iowa Civil and Environmental Engineering/IIHR 4105 Seamans Center Iowa City, IA 52242 Ph. 319-936-0034 email. drew-latta@uiowa.edu ====================================== -----Original Message----- From: Ifeffit [mailto:ifeffit-bounces@millenia.cars.aps.anl.gov] On Behalf Of Simon James Sent: Tuesday, February 26, 2019 3:18 PM To: Ifeffit@millenia.cars.aps.anl.gov Subject: [Ifeffit] Cu K edge XANES stds Hi mailing list, I am hoping someone is willing to share their Cu K-edge XANES spectra from biological Cu thiol complexes. I’m particularly interested in Cu(I/II)-GSH, Cu(I/II)-Cys or similar. I need a sanity check on some fluorescence data I am wrangling. Can anyone help? Best regards, Simon This mail was composed on the move via my phone. Apologies for any typos. Florey Institute of Neuroscience and a Mental Health Melbourne Brain Centre 30 Royal Pde Parkville, 3052 VIC _______________________________________________ Ifeffit mailing list Ifeffit@millenia.cars.aps.anl.gov http://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffit Unsubscribe: http://millenia.cars.aps.anl.gov/mailman/options/ifeffit
Hi Drew,
Thank you for your swift reply. Apologies for the delay in my response but I was dragged in to other matters.
Appreciate the data and ref. Regarding the sanity check I have collected some spatially resolved Cu XANES “maps” of cultured cells and some of the standards I collected during the run are horribly compromised for unclear reasons and I just wanted some clean data to reference while I work on cleaning up (to the degree possible) my standards.
Thanks again.
Cheers,
Simon
Simon James PhD
Senior Research Officer
NHMRC-ARC Dementia Research Development Fellow
Melbourne Dementia Research Centre
University of Melbourne
The Florey Institute of Neuroscience and Mental Health
Web: www.florey.edu.auhttp://www.florey.edu.au
On 28 Feb 2019, at 2:51 am, Latta, Drew E
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Latta, Drew E
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Simon James