Scott, Maybe these refs will help. Rich Mayes New trends in the chemistry of iron(III) citrate complexes: correlations between X-ray structures and solution species probed by electrospray mass spectrometry and kinetics of iron uptake from citrate by iron chelators. Gautier-Luneau, Isabelle; Merle, Claire; Phanon, Delphine; Lebrun, Colette; Biaso, Frederic; Serratrice, Guy; Pierre, Jean-Louis. Chemistry--A European Journal (2005), 11(7), 2207-2219. Synthesis, crystal structure and magnetic property of a binuclear iron(III) citrate complex. Hao, Xiang; Wei, Yongge; Zhang, Shiwei. Transition Metal Chemistry (Dordrecht, Netherlands) (2001), 26(4-5), 384-387. Salicylaldoxime (H2salox) in iron(III) carboxylate chemistry: Synthesis, X-ray crystal structure, spectroscopic characterization and magnetic behavior of trinuclear oxo-centered complexes. Raptopoulou, Catherine P.; Sanakis, Yiannis; Boudalis, Athanassios K.; Psycharis, Vassilis. Polyhedron (2005), 24(5), 711-721.
Hi all,
Anyone out there have a structure (or a reference to a structure) for a carboylate salt of iron(III), e.g. iron(III) acetate or iron(III) citrate? The closest I've found is a really short Nature article from 1965, but I'd like something more quantitative. I'm particularly interested in the Fe-Fe coordination and distance.
--Scott Calvin Sarah Lawrence College
P.S. The mailing list's spam filter has decided that when I send messages from home I am actually engaged in something shady and is blocking me. This is the last day I know I'll be at SLC for a while, so I'm likely to have a hard time responding via the list until this gets straightened out. It's just the Ifeffit list, though--I can still send to people inside the ANL firewall with no problems.
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-- Richard Mayes Barnes Group 450/452 Buehler Hall Department of Chemistry University of Tennessee Knoxville, TN 37996