[Ifeffit] lifetime broadening of pre-edge peaks?

Matthew Marcus mamarcus at lbl.gov
Mon Oct 10 13:23:07 CDT 2011


Thanks.  While none of these have to do with pre-edge peaks such as are found in transition-metal oxides, the assumption of constancy of core-hole broadening does seem to work.
    mam
  ----- Original Message ----- 
  From: Iztok Arčon 
  To: XAFS Analysis using Ifeffit 
  Sent: Monday, October 10, 2011 12:32 AM
  Subject: Re: [Ifeffit] lifetime broadening of pre-edge peaks?


  Dear Matthew

  you can find examples of determination of life-time broadening, deconvolution of XANES specra, and discussion about limitations due to noise in several papers, for example:

  A. Filipponi, J. Phys. B 33, 2835 (2000)

  A. Kodre, I. Arčon, J. Padeznik Gomilšek, R. Frahm
  J. Phys. B: At. Mol. Opt. Phys. 35 (2002) 3497-3513

  A. Kodre, J. Padežnik Gomilšek, A. Mihelič, I. Arcon
  Radiation Physics and  Chemistry 75 (2006) 188-194

  J. Padeznik Gomilsek, I. Arcon, S. de Panfilis, A. Kodre, 
  Phys. Rev. A 79,  (2009) 032514,

  regards
  Iztok

  Matthew Marcus wrote: 
    Is the core-hole lifetime broadening of pre-edge XANES peaks the same as at the main edge?  I'm looking into issues of de-noising of XANES epsctra, so 
    need to figure out how narrow real features can be. 
        mam 
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-- 
prof. dr. Iztok Arcon
University of Nova Gorica
Vipavska 13, POB 301
5001 Nova Gorica, Slovenia

tel: +386 5 331 5227
fax: +386 5 331 5240
e-mail: iztok.arcon at ung.si
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http://www.ung.si/~arcon/xas

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