[Ifeffit] Fe in glassy ceramics
Andrei Shiryaev
a_shiryaev at mail.ru
Wed Feb 16 06:52:38 CST 2011
Dear colleagues,
Probably similar questions were already asked, but nevertheless I would appreciate some advice how to solve the problem.
We are looking at Fe environment in complex glasses, which underwent partial crystallization. A fraction of Fe has precipitated as spinel-like nanocrystals, another fraction remains in glass. Spinel itself is already challenging for XAFS, but our task is to understand the Fe fraction in glass (e.g., Fe-O bond length).
We do not know the exact composition of the crystalline phases, thus we can not record a suitable standard. Does anybody have an idea how could we try to separate the Fe in glass from Fe(cryst) contributions?
I fully realize that the problem is ill-posed, perhaps, some people had somehow solved this problem.
Thanks a lot,
Andrei Shiryaev
Instituteof Physical Chemistry
Moscow
Russia
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