[Ifeffit] Projekt with the "flatten-problem"
Barton, David (DG)
DGBarton at dow.com
Thu Jan 11 10:48:38 CST 2007
Jens,
It appears to me that the E-shift is causing the problems with the step in the pre-edge data. Shelly's data only appears to remove the step because the pre-edge and the extrapolated post-edge plots are nearly parallel. If you adjust the Normalization range in Shelly's data you will see the step appear again.
However, if you set the E-shift to zero and reset Eo, pre-edge range, and normalization range (to your liking) you will see that the step is goes away. So the work around would be to subtract the E-shift from your Raw data, then import into Athena and do not use any E-shift.
Bruce or Matt may have to comment, but it appears to me that the normalization/flatten routine may not be dealing with the E-shift appropriately.
Dave
>-----Original Message-----
>From: ifeffit-bounces at millenia.cars.aps.anl.gov
>[mailto:ifeffit-bounces at millenia.cars.aps.anl.gov] On Behalf
>Of Kelly, Shelly D.
>Sent: Thursday, January 11, 2007 11:11 AM
>To: XAFS Analysis using Ifeffit
>Subject: RE: [Ifeffit] Projekt with the "flatten-problem"
>
>Hi Jens,
>
>I believe the problem is related to the structure in the data
>before E0.
>If you choose e0 to be at the beginning of the structure then
>the normalization is handled better by Athena. Take a look at
>the attached project file. The first data set with e0 on the
>edge as you would choose for EXAFS analysis (e1) shows the
>error that Jens reported. The second data set with a lower
>value for e0 at the beginning of the structure (e2) gets the job done.
>
>Cheers,
>Shelly
>
>---------------------------
>Shelly Kelly
>Argonne National Laboratory
>Bldg 203, RM E113
>9700 S. Cass Ave
>Argonne, IL 60439
>
>Molecular Environmental Science Group
>www.mesg.anl.gov
>skelly at anl.gov
>phone: 630-252-7376
>
>
>> -----Original Message-----
>> From: ifeffit-bounces at millenia.cars.aps.anl.gov [mailto:ifeffit-
>> bounces at millenia.cars.aps.anl.gov] On Behalf Of Jens Kruse
>> Sent: Thursday, January 11, 2007 2:38 AM
>> To: Athena mailing List
>> Subject: [Ifeffit] Projekt with the "flatten-problem"
>>
>> Hi,
>>
>> find attached an example with the "flatten-problem".
>> thanks a lot,
>>
>> jens
>>
>>
>>
>>
>> "Hi,
>>
>> I have a normalization problem with Athena. If I turn on the
>"flatten"
>> option in the background removal section, Athena creates in some of
>the
>> normalized spectra a step in the pre-edge range. How can I get rid
>of
>> it?
>>
>> Thanks,
>>
>> jens"
>
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