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Overview

X-ray absorption fine structure spectroscopy (XAFS) probes the local atomic and chemical environment of a selected atomic species. By analyzing the modulations in the x-ray absorption coefficient at energies just above the x-ray absorption edge threshold, XAFS measurements give quantitative information about coordination species, number, and distance. The x-ray absorption near-edge spectra (XANES) are also sensitive to the valence state of the probe atom.

Principal Techniques

l Near edge (XANES)
l Extended x-ray absorption (EXAFS)
l Grazing incidence XAFS
l Quick - XAFS

 Experiments

l Speciation of metals in soils, sediments and organisms (small number of atoms)
l Grazing incidence studies of cations and anions on surfaces (model systems and natural crystallites)
l Time-resolved studies of reactions on surfaces and interfaces
l High temperature studies (trace elements in melts)
l Oxidation states of planetary materials
l High pressure phases-both in-situ and after quench

Design Team


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Glenn Waychunas

Earth Sciences,  Berkeley Lab, 1 Cyclotron Road, Berkeley, CA 94720; phone : 510-495-2224, fax : 510-486-5686 ; GAWaychunas@lbl.gov

gbrown.gif (16028 bytes) Gordon Brown, Jr.

Department of Geology, Stanford University, Stanford, CA, 94305; phone : 415-723-9168, fax: 415-725-2199; gordon@pangea.stanford.edu

srel.gif (30021 bytes) Paul Bertsch

Savannah River Ecology Laboratory, P.O.Drawer E, University of Georgia, Aiken, SC, 29801;  phone : 803-725-2472, fax: 803-725-3309; bertsch@srel.edu

farges.jpg (3950 bytes) François Farges

Laboratoire des géomatériaux Université Marne la vallée Cité Descartes-Champs S/Marne 77454 Marne la Vallée cedex 2 (France)
and: Stanford University
and: Ecole Nationale Supérieure des Mines de Paris (ENSMP, Paris)
phone: 33 (1) 49 32 90 57, fax: 33 (1) 49 32 91 37; 
farges@univ-mlv.fr      François Farges' Home Page

matt_microprobe.jpg (3950 bytes) Matt Newville

University of Chicago, Builidng 434A, Argonne National Laboratory, 9700 South Cass Ave., Argonne, IL  60439; phone : 630-252-0431, fax : 630-252-0443; newville@cars.uchicago.edu      Matt Newville's Home Page