-----Original Message-----
From: ifeffit-bounces@millenia.cars.aps.anl.gov [mailto:ifeffit-bounces@millenia.cars.aps.anl.gov] On Behalf Of Paul Fons
Sent: Tuesday, April 27, 2004 7:59 PM
To: XAFS Analysis using Ifeffit
Subject: Re: [Ifeffit] Substrate material questionI have still not decided on the final substrate material, but I have a couple of samples coming from Dupont of polyimide (same composition as Kapton) material called vespel. It is essentially inert as one would expect (like Kapton), but due to differences in manufacture I understand it is hydroscopic. From this I assume that the reaction for making Kapton is diffusion limited and Vespel is essentially a "polycrystalline" -- in the sense there are grains between which water can absorb -- form of Kapton. The energy in question is 11.6 keV (the Ge edge). Si is an interesting idea but the loss for a 200 micron thick substrate is essentially 1/e. It is certainly worth considering for higher energies though! The 1/e value for polyimide is about 3500 microns in contrast, while the 1/e value for MgO is about 300. As in my experiment I want to create biaxial stress in a thin film on the substrate, I worry that the stress/strain curves for MgO are too stiff. On the other hand, thin Si is a real possibility (darn, Si technology is everywhere!). I like the Si idea and might try that in parallel. Has anyone tried using thinned Si wafers (Virginia Technology ? sells mechanically thinned wafers I think -- I saw them at a MRS booth a long time ago). How fragile are the wafers?
On 2004/04/28, at 0:32, Jeff Terry wrote:
Hi Matt,
Both items are good to know. I didn't realize that the laminated kapton structures still had good heat resistance.
Jeff
On Apr 27, 2004, at 10:22 AM, Matt Newville wrote:
Hi Paul,
I think you can get polyimide thicker than 175 microns. It may notgo as Kapton, but maybe as Cirlex or Torlon or something else. Ithink goodfellow.com carries these in millimeter thick sheets androds, and that they're still radiation and heat resistant.Goodfellow tends to be pricey, but has excellent information onthermal and mechanical properties.
Using MgO, sapphire, or even diamond might be reasonable too.
--Matt
PS: I have a working build of PGPLOT with all of Aquaterm, X11,Postscript, and Png devices on Mac OS X. I'm still tweakingthe makefile so that it links directly to the png objects toavoid possible conflicts with dynamic png and zlib libraries,but I should have a working ifeffit binary using this in amatter of days, and then be ready to tweak horae's Makefile.PLso that horae_update works.
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_______________________________________________Ifeffit mailing listIfeffit@millenia.cars.aps.anl.govhttp://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffitDr. Paul FonsSenior ResearcherNational Institute for Advanced Industrial Science & TechnologyMETICenter for Applied Near-Field Optics Research (CANFOR)AIST Central 4, Higashi 1-1-1Tsukuba, Ibaraki JAPAN 305-8568
tel. +81-298-61-5636fax. +81-298-61-2939
email: paul-fons@aist.go.jp
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〒305−8568茨城県つくば市東1−1−1つくば中央第4近接場光応用工学センターポール・フォンス主任研究官