Hi all, I was following this article about Li2TiS3 https: //pubs. acs. org/doi/full/10. 1021/acs. inorgchem. 4c03864 and found this Ti edge XANES figure The authors claim The peak position for LTS-213 is approximately 4970 eV, which agrees well with
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Hi all,
I was following this article about Li2TiS3

https://pubs.acs.org/doi/full/10.1021/acs.inorgchem.4c03864

and found this Ti edge XANES figure

image.png
The authors claim

The peak position for LTS-213 is approximately 4970 eV, which agrees well with that for rutile TiO2 with a valence of titanium species in the 4+ oxidation state.

Should we use the pre-edge to determine the oxidation state? Is it reliable, or should we use E₀ and compare it with references of well-known oxidation states?
 
In addition, TiS2, in which titanium is also in the 4+ oxidation state, shows pre-edge peaks at 4968–4971 eV. (21) Considering the titanium oxidation state in the raw materials, the stability of the titanium species, and the XANES results, the oxidation state of the titanium species in LTS-213 is likely to be 4+.

The second conclusion is even more unclear.

Would you help me see if I am missing something in my understanding of oxidation states using XANES?


Best, B.