Chris,
In cases where intense pre-edge features are observed, such as the one you attached, you should manually set the Eo and not accept the Athena defaults. I usually start with half-way up the absorption edge (you can look at the derivative and move the Eo value to the maximum in the derivative; however, make sure you don't move it back to the pre-edge).
More detailed information on setting Eo and background removal can be found here:
http://cars9.uchicago.edu/~ravel/software/doc/Athena/html/index.html
Also, www.xafs.org is an excellent resource for more information.
-Richard
I forgot to post a bitmap of the spectra of the previous message. Thank you all.
--
Christopher J. Patridge
Graduate Student
SUNY Buffalo - Dept of Chemistry
716-645-6800 x 2110
315-529-0501
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