Hi all,
@Ganga,
I agree both with Mike and Dean. The pre-edge Features are very strong, to say the least. I am wondering if this Anaerobic MBR Technology helps towards the Formation of other forms of P. Maybe Phosphonates?
Also, how is your heavy metal Content? I have seen some lead Phosphates that have a very strong pre-edge. Altouugh the second pre-edge feature I have never seen.
Perhaps you could look into These spectra, altough might be far fetched to your System.
https://www.sciencedirect.com/science/article/abs/pii/S0022286018313723
Phosphine metal–organic frameworks
https://pubs.rsc.org/en/content/articlepdf/2015/cp/c4cp05151c
Kind regards
Luis
From: Dean Hesterberg
Sent: 16 October 2020 20:19
To: XAFS Analysis using Ifeffit
Subject: Re: [Ifeffit] Ifeffit Digest, Vol 212, Issue 7
Mike made a very good point. Both of the lower-energy features do seem unusually intense relative to the normalized background, at least in comparison to most Fe or Al bonded phosphate species that I've seen.
On Fri, Oct 16, 2020 at 1:56 PM Mike Massey <mmassey@gmail.com> wrote:
Hmm fair enough. I'm not necessarily claiming it's not a "real" feature, but I would definitely be cautious of going looking for an interpretation of this one until I was absolutely sure.
To me, 5000 ppm potentially seems a bit high still, but I don't know the detector or setup you're using, or how many replicate spectra you are comfortable with taking. Maybe a 2:1 or 3:1 dilution would at least be worth trying, just from looking at the spectrum it seems like you may have room to go lower.
But I'm also curious to dig through my notes and data so I'll do that as soon as I can, too.
Cheers,
Mike
> On Oct 17, 2020, at 1:29 AM, Ganga Hettiarachchi <ganga@ksu.edu> wrote:
>
> Hello Dean,
> Thanks for this interpretation; it makes sense. I was (am still) quite surprised by the intense of Al(III) pre-edge feature as we did not detect anything else in our XRD work, except some Fe oxides (the product is X-ray amorphous most likely).
>
> Hello Mike,
> Thanks. We diluted this sample already to bring P concentration below 5000 mg/kg. We can potentially try further diluting, but when we go below that, sometimes we have a hard time getting a reasonable P spectrum in environmental samples.
>
> Best regards,
>
> Ganga
>
> --------------------
>
> Ganga M. Hettiarachchi, Ph.D.
> Professor of Soil and Environmental Chemistry
> Department of Agronomy
> 2107 Throckmorton Plant Sciences Center
> 1712 Claflin Road
> Kansas State University
> Manhattan, KS 66506 USA
>
> 785-532-7209 (office)
> 785-532-6094 (FAX)
>
> http://www.agronomy.k-state.edu/research/soil-and-environment/soil-environment-chem/
> http://www.agronomy.k-state.edu/people/faculty/hettiarachchi-ganga/index.html
>
> -----Original Message-----
> From: Ifeffit [mailto:ifeffit-bounces@millenia.cars.aps.anl.gov] On Behalf Of ifeffit-request@millenia.cars.aps.anl.gov
> Sent: Friday, October 16, 2020 4:53 AM
> To: ifeffit@millenia.cars.aps.anl.gov
> Subject: Ifeffit Digest, Vol 212, Issue 7
>
> Send Ifeffit mailing list submissions to
> ifeffit@millenia.cars.aps.anl.gov
>
> To subscribe or unsubscribe via the World Wide Web, visit
> http://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffit
> or, via email, send a message with subject or body 'help' to
> ifeffit-request@millenia.cars.aps.anl.gov
>
> You can reach the person managing the list at
> ifeffit-owner@millenia.cars.aps.anl.gov
>
> When replying, please edit your Subject line so it is more specific than "Re: Contents of Ifeffit digest..."
>
>
> Today's Topics:
>
> 1. Re: P K-edge XANES spectrum question (Dean Hesterberg)
> 2. Re: P K-edge XANES spectrum question (Mike Massey)
>
>
> ----------------------------------------------------------------------
>
> Message: 1
> Date: Fri, 16 Oct 2020 05:21:58 -0400
> From: Dean Hesterberg <dean_hesterberg@ncsu.edu>
> To: XAFS Analysis using Ifeffit <ifeffit@millenia.cars.aps.anl.gov>
> Subject: Re: [Ifeffit] P K-edge XANES spectrum question
> Message-ID:
> <CANEgao_RuxGJ7khkrwypyqu4FM333aw3iozgtPJHuZP6Sx9KSA@mail.gmail.com>
> Content-Type: text/plain; charset="utf-8"
>
> Hello Ganga,
>
> That is a very interesting spectrum. Given what you said about the system, the lower energy feature at ~ 2146 eV should be Fe(III)-bonded phosphate and the feature at ~2149 eV should be Al(III)-bonded phosphate. Both produce pre-white line absorption peaks, but the Al-bonded phosphate peak is closer to the white line and less distinct in spectra of Al-phosphates like variscite and non-crystalline Al-phosphate, for example (see Khare et al. 2007. *Geochimica et Cosmochimica Acta* 71:4405, Fig. 5C). A significant proportion of the phosphate in your system apparently precipitated with Al-13 polymer structures in the aluminum chlorohydrate.
>
> Dean
>
>> On Fri, Oct 16, 2020 at 1:26 AM Ganga Hettiarachchi <ganga@ksu.edu> wrote:
>>
>> All,
>>
>> Can anyone provide some insight into the pre-edge ?features? in this P
>> XANES spectrum?
>>
>> This is the P XANES spectrum we got for a recovered P-product (rich in
>> Fe and Al) from wastewater using the AnMBR technology. During the
>> coagulation process, our collaborators (environmental engineers) used
>> stock solutions of aluminum chlorohydrate (ACH) and FeCl3.
>>
>>
>>
>> Thanks very much.
>>
>>
>>
>> Best regards,
>>
>>
>>
>> Ganga
>>
>>
>>
>> --------------------
>>
>>
>>
>> Ganga M. Hettiarachchi, Ph.D.
>>
>> Professor of Soil and Environmental Chemistry
>>
>> Department of Agronomy
>>
>> 2107 Throckmorton Plant Sciences Center
>>
>> 1712 Claflin Road
>>
>> Kansas State University
>>
>> Manhattan, KS 66506 USA
>>
>>
>>
>> 785-532-7209 (office)
>>
>> 785-532-6094 (FAX)
>>
>>
>>
>>
>> http://www.agronomy.k-state.edu/research/soil-and-environment/soil-env
>> ironment-chem/
>>
>>
>> http://www.agronomy.k-state.edu/people/faculty/hettiarachchi-ganga/ind
>> ex.html
>>
>>
>> _______________________________________________
>> Ifeffit mailing list
>> Ifeffit@millenia.cars.aps.anl.gov
>> http://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffit
>> Unsubscribe: http://millenia.cars.aps.anl.gov/mailman/options/ifeffit
>>
>
>
> --
> DEAN HESTERBERG
> William Neal Reynolds Distinguished Professor of Soil Chemistry Dept. of Crop and Soil Sciences NC State University
>
> email: dean_hesterberg@ncsu.edu
> -------------- next part --------------
> An HTML attachment was scrubbed...
> URL: <http://millenia.cars.aps.anl.gov/pipermail/ifeffit/attachments/20201016/0cabbec7/attachment-0001.htm>
>
> ------------------------------
>
> Message: 2
> Date: Fri, 16 Oct 2020 22:52:52 +1300
> From: Mike Massey <mmassey@gmail.com>
> To: XAFS Analysis using Ifeffit <ifeffit@millenia.cars.aps.anl.gov>
> Subject: Re: [Ifeffit] P K-edge XANES spectrum question
> Message-ID: <3697CB1C-9CA1-46AE-A6A7-828A886BDD3F@gmail.com>
> Content-Type: text/plain; charset="utf-8"
>
> I recommend diluting this sample by a lot (20x maybe, or more) and collecting another spectrum. I've had instances of strange features in P spectra that ended up being weird self-absorption type artifacts.
>
> I will dig through the spectra I have from similar samples, this one reminds me of a spectrum I saw once, perhaps in a similar system...It would be interesting if we inadvertently got similar results. Thanks for sharing!
>
>
>
> Mike
>
>
>
>
>
>> On Oct 16, 2020, at 10:22 PM, Dean Hesterberg <dean_hesterberg@ncsu.edu> wrote:
>>
>> ?
>> Hello Ganga,
>>
>> That is a very interesting spectrum. Given what you said about the system, the lower energy feature at ~ 2146 eV should be Fe(III)-bonded phosphate and the feature at ~2149 eV should be Al(III)-bonded phosphate. Both produce pre-white line absorption peaks, but the Al-bonded phosphate peak is closer to the white line and less distinct in spectra of Al-phosphates like variscite and non-crystalline Al-phosphate, for example (see Khare et al. 2007. Geochimica et Cosmochimica Acta 71:4405, Fig. 5C). A significant proportion of the phosphate in your system apparently precipitated with Al-13 polymer structures in the aluminum chlorohydrate.
>>
>> Dean
>>
>>>> On Fri, Oct 16, 2020 at 1:26 AM Ganga Hettiarachchi <ganga@ksu.edu> wrote:
>>> All,
>>>
>>> Can anyone provide some insight into the pre-edge ?features? in this P XANES spectrum?
>>>
>>> This is the P XANES spectrum we got for a recovered P-product (rich in Fe and Al) from wastewater using the AnMBR technology. During the coagulation process, our collaborators (environmental engineers) used stock solutions of aluminum chlorohydrate (ACH) and FeCl3.
>>>
>>>
>>>
>>> Thanks very much.
>>>
>>>
>>>
>>> Best regards,
>>>
>>>
>>>
>>> Ganga
>>>
>>>
>>>
>>> --------------------
>>>
>>>
>>>
>>> Ganga M. Hettiarachchi, Ph.D.
>>>
>>> Professor of Soil and Environmental Chemistry
>>>
>>> Department of Agronomy
>>>
>>> 2107 Throckmorton Plant Sciences Center
>>>
>>> 1712 Claflin Road
>>>
>>> Kansas State University
>>>
>>> Manhattan, KS 66506 USA
>>>
>>>
>>>
>>> 785-532-7209 (office)
>>>
>>> 785-532-6094 (FAX)
>>>
>>>
>>>
>>> http://www.agronomy.k-state.edu/research/soil-and-environment/soil-en
>>> vironment-chem/
>>> http://www.agronomy.k-state.edu/people/faculty/hettiarachchi-ganga/in
>>> dex.html
>>>
>>>
>>>
>>> _______________________________________________
>>> Ifeffit mailing list
>>> Ifeffit@millenia.cars.aps.anl.gov
>>> http://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffit
>>> Unsubscribe: http://millenia.cars.aps.anl.gov/mailman/options/ifeffit
>>
>>
>> --
>> DEAN HESTERBERG
>> William Neal Reynolds Distinguished Professor of Soil Chemistry Dept.
>> of Crop and Soil Sciences NC State University
>>
>> email: dean_hesterberg@ncsu.edu
>> _______________________________________________
>> Ifeffit mailing list
>> Ifeffit@millenia.cars.aps.anl.gov
>> http://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffit
>> Unsubscribe: http://millenia.cars.aps.anl.gov/mailman/options/ifeffit
> -------------- next part --------------
> An HTML attachment was scrubbed...
> URL: <http://millenia.cars.aps.anl.gov/pipermail/ifeffit/attachments/20201016/324bba53/attachment.htm>
>
> ------------------------------
>
> Subject: Digest Footer
>
> _______________________________________________
> Ifeffit mailing list
> Ifeffit@millenia.cars.aps.anl.gov
> http://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffit
> Unsubscribe: http://millenia.cars.aps.anl.gov/mailman/options/ifeffit
>
>
> ------------------------------
>
> End of Ifeffit Digest, Vol 212, Issue 7
> ***************************************
>
> _______________________________________________
> Ifeffit mailing list
> Ifeffit@millenia.cars.aps.anl.gov
> http://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffit
> Unsubscribe: http://millenia.cars.aps.anl.gov/mailman/options/ifeffit
_______________________________________________
Ifeffit mailing list
Ifeffit@millenia.cars.aps.anl.gov
http://millenia.cars.aps.anl.gov/mailman/listinfo/ifeffit
Unsubscribe: http://millenia.cars.aps.anl.gov/mailman/options/ifeffit
--
DEAN HESTERBERG
William Neal Reynolds Distinguished Professor of Soil Chemistry
Dept. of Crop and Soil Sciences
NC State University
email: dean_hesterberg@ncsu.edu