Hi Matt,
I imagined you might not remember about the data or how was it prepared, so I decided not to bother you asking about it. But sounds like you do have an amazing memory.
Yes, I would be happy to characterize the sample by running both EXAFS and XRD on it if you still have it. I would of course share the information with the mailing list, once I characterize it. I will collect the sample from you sometime soon. Thanks again for offering.
Regards,
Bhoopesh
Hi Bhoopesh,
It's amazing to me how many people have asked about this data set.
I did not prepare the sample of Fe3C measured for the data in the
model compound library. Basically, a user interested in reduced iron
phases and with good knowledge of carbides showed up at the beamline
with a vial of black powder marked Fe3C. We made a powder-on-tape
sample of this and measured it. At the time, the user (who knows
about diamond synthesis and who I trust) said the sample was made by
another colleague. Yes, it all sounds "secret formula", and I do not
know whether it is pure cementite. If you're interested, believe I
still have this sample in my Standards Notebook if you'd like to
measure XAFS or XRD on it.
--Matt
On Thu, Sep 24, 2009 at 4:08 PM, Bhoopesh Mishra <bhoopeshm@gmail.com> wrote:
> Hi Scott and Mathew,
> Thanks for pointing me to Matt Newville's archive. It is a great
> resource to have and I have used it on several occasions.
>
> However, what I found on that database is "Fe3C". Since there are
> couple of different local environments for Fe3C, and not all of them are
> Cementite - I am not sure if that would be a good standard for me.
> Nevertheless, it served as a good starting point.
>
> It would be great if Andrew can send us his data.
>
>
> Thanks again,
> Bhoopesh
>
>
>
> On Thu, Sep 24, 2009 at 11:54 AM, Scott Calvin <SCalvin@slc.edu> wrote:
>>
>> Hi Bhoopesh,
>>
>> There are files that are identified as cementite in Matt Newville's
>> archive:
>>
>> http://cars9.uchicago.edu/~newville/ModelLib/search.html
>>
>> If you manage to get any other data, let me know; I've used the
>> standard at the link above, but I'd like to confirm it.
>>
>> --Scott Calvin
>> Sarah Lawrence College
>>
>> On Sep 24, 2009, at 11:45 AM, bhoopeshm wrote:
>>
>> > Dear All,
>> > I am writing to see if anyone on this mailing list has
>> > ever measured "Cementite" (Fe3C) EXAFS. It is basically an Iron
>> > Carbide, nothing exotic at all.
>> >
>> > I would be very grateful to anyone who might want to share an EXAFS
>> > spectrum of Cementite (Fe3C).
>> >
>> >
>> > Regards,
>> > Bhoopesh
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>
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